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聚乙烯PTC材料的交联和凝胶率

[摘要]
经辐射交联的PTC导电复合材料, 其碳黑粒子牢固地附着在聚乙烯的交联网络上, 即使在高于聚乙烯熔融温度用沸腾的溶剂长时间回流, 碳黑粒子也不会从交联网络上分离, 限制了碳黑粒子在高温的随机运动, 明显改善了材料的机械稳定性、热稳定性及电稳定性。本文采用溶剂萃取法测定凝胶率,讨论了PTC复合材料的交联效应、添加剂与凝胶率、辐射剂量与凝胶率的关系。
[英文摘要]
The carbon black particles are strongly attached to a cross-linked polyethylene network, and they can not be separated from the network even by refluxing in a boiling xylene for many hours at the temperature higher than the melting point of cross-linked polyethylene. It is thus expected to reduce the free movement of the carbon black particles at high temperatures, and to greatly improve mechanical, thermal and electrical stability. The degree of the cross-link is determined in a gel reflux extraction, and the relation among the cross-link effect, additives and gel fraction is discussed.(5 refs.)
[关键词]
辐射交联 PTC效应 凝胶率 有机复合材料
[作者]
陈汴琨 吴红涛 章子元 武于东 王济娥
[作者单位]
(北京航空航天大学 北京 100083)
[刊名]
电子元件与材料
[英文刊名]
ELECTRONIC COMPONENTS&MATERIALS
[期刊类别]
无线电电子学与电信技术
[年 卷 期]
1999   18   1

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